New PDF release: Anodic Oxidation

By Sidney D. Ross, Manuel Finkelstein and Eric J. Rudd (Eds.)

ISBN-10: 012597650X

ISBN-13: 9780125976503

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The i-E relationship. In the derivation of the rate equations thus far, it has been assumed that a one electron-transfer, single-step reaction was involved. In other words the single occurrence of an electron transfer led to the single occurrence of the overall reaction. This is not always true of electrode processes as is exemplified by the oxidation of carboxylate anions (the Kolbe electrosynthesis) to a hydrocarbon, where two electron transfer steps must occur to yield 1 mole of the product: / / / .

2. J. Heyrovsky, Chem. Listy. 16, 256 (1922). 3. J. " Academic Press, New York, 1966. 4. P. " Wiley (Interscience), New York, 1954. 5. O. H. Muller, in "Physical Methods of Organic Chemistry" (A. ), Vol. I, Part IV, p. 3155. Wiley (Interscience), New York, 1960. 6. P. " Macmillan, New York, 1964. 7. C. L. Perrin, Prog. Phys. Org. Chem. 3, 165 (1965). 8. P. Zuman and S. Wawzonek, in "Progress in Polarography" (P. Zuman and I. M. ), Vol. I, p. 303. Wiley (Interscience), New York, 1962. 9. J. E. Page, Quart.

Harrison,/. Electroanal. Chem. 21, 387 (1969). 44 References 45 29. P. " Wiley (Interscience), New York, 1965. 30. A. N. Frumkin, Z. Phys. 35, 792 (1926). 31. J. O'M. Bockris and A. K. N. Reddy, "Modern Electrochemistry," Vol. 2, Chapter 8. Plenum, New York, 1970. 32. B. E. Conway, Prog. Kinet. 4, 399 (1967). 33. H. H. Bauer, / . Electroanal Chem. 16, 419 (1968). 34. A. N. Frumkin, Z. Phys. ,, Abt. A 160, 116 (1932). 35. J. N. Bronsted, Chem. Rev. 5, 231 (1928). 36. L. I. Krishtalik, Elektrokhimiya 2, 1123 (1966); / .

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Anodic Oxidation by Sidney D. Ross, Manuel Finkelstein and Eric J. Rudd (Eds.)

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