By James Morrison (Eds.)
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7) gives Cx 2(x + R + 2E) 0 2(x + R) ' (8) If Eq. (8) is written in terms of ee, it becomes Cx 0 2[x + y(\ + ee)] 2[x + j ( l - ee)] * (9) 50 Κ. Κ. A n d e r s e n , D. Μ. Gash, a n d J. D . Robertson There is the possibility of preparing a sample of pure isotopically labeled enantiomer from, for example, a natural product. In this case, assuming as above that the ( + )-enantiomer is prepared, Eq. y/2)(l + ee)] " Equation (9) can be rearranged thus: \_ ee 1/2 (χ + y) - + y) 2 y (11) or (ee) 2 C (x + y) - C x(x + y) 2 = ± 0 yc 2 (12) ± Consider now the situation in which the isolated material is not a racemic modification (a labeled racemic modification is still used as the tracer; Fig.
Asymmetric Synthesis by James Morrison (Eds.)