By Gotthold Ebert (auth.)
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Additional info for Biomimetic and Bioorganic Chemistry
Cited from Ref. 37)) 47 Mitsuo Okahara, Yohji Nakatsuji system in a slightly acidic solution, since the release process is accelerated by the protonation to the ring nitrogen, However, the introduction of an amide group for the purpose of increasing the lipophilicity lowers the stability constant for alkali metal cations 4s) and may decrease the recognition ability for such guest ions compared with normal crown ether derivatives. 0 0 0 HOOC~e" "~0 (P ~ = polymer 0-- ~,/0,,,~ h0; ( ~ =from acrytoy[ chloride gl ; ( ~ =from styrene-acryloyl chloride (1:1} g2; ( ~ =from styrene-acryloyl chloride (5:1) •~ C H 2 - CHz-- C H - - C H ~ C H 2 - - C H 2 -- C H -- CH l c=oJ~ II I C=O!
260, 131 (1982) 115. , Kuroyanagi, Y. , Orgel, L. : Int. J. Peptide Protein Res. : J. Am. Chem. Soc. : Int. J. Biol. Macromol. 5, 109 (1983) Epand, R. , Scheraga, H. A. : Biopolymers 6, 1383 (1968) Arfmann, H. , Wagner, K. G. : Biopolymers 14, 1381 (1975) Zander, R. : Schriftenreihe des Deutschen Wollforschungs-Instituts, Sonderband 1979, p. t03, Aachen 1979 124. : J. biol. Chem. 245, 3335 (1970) t25. : J. C. S. Faraday I 73, 203 (1977) 126. , Iijima, T. : J. C. S. Faraday I 74, 2583 (1978) 127.
A schematicmechanism for the carrier mediated countertransport of a metal ion and a proton. (Cited from Ref. 29)) The same investigators recently synthesized crown-6 derivatives having two carboxyl groups (25-30) and investigated their transport abilities for alkaline earth cations 31,32). Despite the complexing ability of the complexes formed, the rate of transport attained by these cations is comparable to that of cations with single charge. Some carriers show selectivity to Sr2+ and Ba 2÷ (Table 5).
Biomimetic and Bioorganic Chemistry by Gotthold Ebert (auth.)